Лабораторія 14.1

Laboratory of polymer modification

Head of Laboratory

Rogalsky Sergey Petrovich, Candidate of Chemical Sciences
         Tel. + 38 044 5594622;
         Email: sergey.rogalsky@gmail.com

Main areas of research:

  • synthesis of modifying impurities for industrial polymers with improved performance: plasticizers for industrial thermoplastics with high migration resistance, heat-resistant biocides with low toxicity, anti-fouling agents and corrosion inhibitors for protective coatings;
  • synthesis of new monomers - internal rheological properties modifiers for polycondensation polymers;
  • surface chemical modification of polymers for medical purposes;
  • synthesis of new proton-conducting electrolytes based on ionic liquids and obtaining polymer-electrolyte membranes for fuel cells operated at temperatures above 100 °C.

Scientific projects:

“Obtaining and Study of Properties of New Antimicrobial Polymer Composites, Modified by Functionalized Onium Salts of Heterocyclic Nature” (2018-2020)

“Eco-friendly plasticizers for polyvinyl chloride based on vegetable oil derivatives” (2017-2021)

“Proton-conducting polymeric membranes based on ionic liquids” (2013-2017)

Ionene Synthesis (STCU Project No. R-536, 2012)

Modification of Polycarbonates by Ionic Compounds (2010-2012)

“Development of selective composite membranes based on porous polymeric structures and ionic liquids” (CNRS Project, 2010-2011)

Guanidine Derivation Synthesis (PPG Industries, USA) (2007)

“Internal Modification of Polycarbonates” (STCU Project No. 3770, 2006-2009)

“Application of ionic liquids for modification of polyamides” (2007-2009)

Dzhuzha Oleg Vitaliyovych, Researcher, Candidate of Technical Sciences in the specialty 21.06.01 “Environmental Safety” (2009)

Oksenia Aksenovskaya, Junior Researcher, Candidate of Chemical Sciences in the specialty 02.00.06 “Chemistry of Macromolecular Compounds” (2014)

Oksana Tarasyuk, Junior Researcher

Publications:

2018

S. Rogalsky, J.-F. Bardeau, S. Makhno, N. Babkina, O. Tarasyuk, T. Cherniavska, I. Orlovska, N. Kozyrovska, O. Brovko. New proton conducting membrane based on bacterial cellulose/polyaniline nanocomposite film impregnated with guanidinium-based ionic liquid. Polymer. – 2018, Vol. 142. – pp. 183-195.

K. Fatyeyeva, S. Rogalsky, O. Tarasyuk, C. Chappey, S. Marais. Vapour sorption and permeation behaviour of supported ionic liquid membranes: application for organic solvent/water separation. Reactive and functional polymers – 2018, Vol.130. – pp.16-28.

A.Vashchuk, A. Rios de Anda, O. Starostenko, O.Grigoryeva, P. Sotta, S. Rogalsky, P. Smertenko, A.
Fainleib, D. Grande. Structure . property relationships in nanocomposites based on cyanate ester resins
and 1-heptyl pyridinium tetrafluoroborate ionic liquid. Polymer. – 2018, Vol.148. – pp. 14-26. 2017

S. Ghamrawi, J.-P. Bouchara, O. Tarasyuk, S. Rogalsky, L. Lyoshina, O. Bulko, J.-F. Bardeau. Promising silicones modified with cationic biocides for the development of antimicrobial medical devices. Materials Science and Engineering C. – 2017, Vol. 75. – pp. 969-979.

M. Trush, I. Semenyuta, S. Vdovenko, S. Rogalsky, E. Lobko, L. Metelytsia. Synthesis, spectroscopic and molecular docking studies of imidazolium and pyridinium based ionic liquids with HSA as potential antimicrobial agents. Journal of Molecular Structure – 2017, Vol. 1137. – pp. 692-699.

A. Protasov, J.-F. Bardeau, I. Morozovskaya, M. Boretska, T. Cherniavska, L. Petrus, O. Tarasyuk, L.
Metelytsia, I. Kopernyk, L. Kalashnikova, O. Dzhuzha, S. Rogalsky. New promising antifouling agent based on polymeric biocide polyhexamethylene guanidine molybdate. Environmental Toxicology and Chemistry – 2017, Vol. 36 – pp. 2543 – 2551.

A. Fainleib, A. Vashchuk, O. Starostenko, O. Grigoryeva,S. Rogalsky, T.-T. Nguyen, D. Grande. Nanoporous polymer films of cyanate ester resins designed by using ionic liquids as porogens. Nanoscale Research Letters. – 2017, Vol. 12. – p. 126.

2016

D. Hodyna, J.-F. Bardeau, L. Metelytsia, S. Riabov, L. Kobrina, S. Laptiy, L. Kalashnikova, V.
Parkhomenko, O. Tarasyuk, S. Rogalsky. Efficient Antimicrobial Activity and Reduced Toxicity of 1-Dodecyl-3-Methyl-Imidazolium Tetrafluoroborate Ionic Liquid/.-Cyclodextrin Complex. Chemical
Engineering Journal – 2016, Vol. 284. – pp. 1136-1145.

D. Hodyna, V. Kovalishyn, S. Rogalsky, V. Blagodatnyi, K. Petko, L. Metelytsia. Antibacterial activity of imidazolium-based ionic liquids investigated by QSAR modelling and experimental studies. Chemical Biology & Drug Design – 2016. – Vol. 88, Issue 3. – pp. 422–433.

S. Rogalsky, J.-F. Bardeau, H. Wu, L. Lyoshina, O. Bulko, O. Tarasyuk, S. Makhno, T. Cherniavska, Y. Kyselov, J. H. Koo. Structural, thermal and antibacterial properties of polyamide 11/polymeric biocide polyhexamethylene guanidine dodecylbenzenesulfonate composites. Journal of Material Science. – 2016. – Vol. 51. – pp. 7716–7730.

A. Fainleib, O. Grigoryeva, O. Starostenko, A. Vashchuk, S. Rogalsky, D. Grande. Acceleration effect of ionic liquids on polycyclotrimerization of dicyanate esters. Express Polymer Letters. – 2016, Vol. 10, №9. – pp. 722-729.

2015

A. Dahi, K. Fatyeyeva, D. Langevin, C. Chappey, S. Rogalsky, O. Tarasyuk, S. Marais. Water sorption properties of room-temperature ionic liquids over the whole range of water activity and molecular state of water in these media. RCS Advances. – 2015, Vol. 5. – pp. 76927-76938.

2014

S. Rogalsky, K. Fatyeyeva, L. Lyoshina, O. Tarasyuk, O. Bulko, S. Lobok. Antimicrobial properties and thermal stability of polycarbonate modified with 1-alkyl-3-methylimidazolium tetrafluoroborate ionic
liquids. Journal of Applied Polymer Sciences. – 2014, Vol.131, Issue 7 – APP.40050.

A. Dahi, K. Fatyeyeva, D. Langevin, C. Chappey, S. Rogalsky, O. Tarasyuk, S. Marais. Polyamide/ionic liquid composite membranes for fuel cells operating at high temperatures. Electrochimica Acta. – 2014. –
Vol. 130. – pp. 830-840

A. Dahi, K. Fatyeyeva, D. Langevin, C. Chappey, S. Rogalsky, O. Tarasyuk, A. Benamor, S. Marais. Supported ionic liquid membranes for water and volatile organic compounds separation: Sorption and permeation properties. Journal of Membrane Sciences. – 2014, Vol. 458. – pp. 164-178.

O. Kukharenko, J.-F. Bardeau, I. Zaets, L. Ovcharenko, O. Tarasyuk, S. Porhyn, I. Mischenko, A. Vovk, S. Rogalsky, N. Kozyrovska. Promising low cost antimicrobial composite material based on bacterial cellulose and polyhexamethylene guanidine hydrochloride. European Polymer Journal. – 2014, Vol. 60. – pp. 247-254.

S. Rogalskyy, J.-F. Bardeau, O. Tarasyuk, K. Fatyeyeva. Fabrication of new antifungal polyamide-12 material. Polymer International. – 2012, Vol. 61. – pp. 686-691.